Wakefield, Jennifer
(2021)
Natural polymers for consolidation of the Oseberg artefacts.
PhD thesis, University of Nottingham.
Abstract
Conservation is of vital importance for museums. The Viking Ship Museum has a particular problem in terms of conservation. It houses artefacts from the Oseberg Viking ship burial that are of great significance in terms of Viking history and are of national pride to Norway. These artefacts were buried in 834 AD, excavated in 1904, treated with alum and dried. The alum treatment, which started in 1905, led to them becoming acidic (pH 1-2), resulting in severe degradation of the artefacts. Current conservation methods have their limitations due to the alum previously used to conserve these artefacts, the removal of which could cause some of the most fragile artefacts to collapse entirely. However, some of the less fragile artefacts could cope with a water treatment. Even in that case, PEG, the most commonly used aqueous conservation treatment, may not be suitable due to the high concentration of acid and metal ions in some artefacts. Natural polymers pose some advantages to traditional methods in terms of sustainability and future use, so, for this reason, chitosan was initially investigated. Additionally, chitosan contains amine groups which may help to increase the pH and aid in metal chelation and in preventing hydrolysis reactions. The molecular weight of potential consolidants was determined with an analytical ultracentrifuge prior to wood treatment to determine the likelihood of wood penetration. This was followed by testing on artificially degraded wood and on archaeological wood. Chitosan gave good results in wood treatment tests, however, the use of acid for the dissolution of chitosan is a concern, hence, despite obtaining good results, an alternative aqueous treatment was sought. Chitosan acetate salt and aminocellulose were researched using the same methodology. Chitosan acetate salt did not aid in consolidation. Aminocellulose produced good results for conservation, appearing suitable either alone or in combination with PEG and has potential advantages to PEG, although the long-term stability needs to be assessed.
For where an aqueous treatment could not be used this study investigated a silyl modified chitosan, already known to be soluble in organic solvents. The reaction was successfully carried out with the chitosan of desired molecular weight, which ensured penetration into the wood. The silyl modified chitosan was however, found to be very brittle and therefore not suitable for conservation. For comparison during this investigation known consolidants paraloid B72 and butvar B98 were also investigated. B72 appears suitable for immersion as a pre-consolidant, to be followed by washing out the acid and alum, or to be used in combination with calcium hydroxide nanoparticles. B98 appears preferable for injection. However, long term acid stability needs assessed: if stable, B98 may be suitable even without removal of alum; alternatively, it could be used in combination with calcium hydroxide.
This research demonstrates aminocellulose as a possible aqueous treatment and B72 or B98 as non-aqueous treatments. Stability of aminocellulose needs to be assessed and B72 and B98 require exploring in combination with calcium hydroxide. Mechanical testing and long-term stability require further investigation. These treatments may prove to be suitable consolidants for the Oseberg artefacts. In particular, aminocellulose could aid in the conservation of other artefacts with high acid and iron content, including newly discovered waterlogged artefacts.
| Item Type: |
Thesis (University of Nottingham only)
(PhD)
|
| Supervisors: |
Harding, Stephen
Stockman, Robert
Braovac, Susan
Adams, Gary |
| Keywords: |
Archaeological conservation, Analytical ultracentrifuge (AUC), Oseberg, Wood conservation, Chitosan, Aminocellulose, Natural polymers, Consolidants |
| Subjects: |
C Auxiliary sciences of history > CC Archaeology
Q Science > QD Chemistry > QD241 Organic chemistry > QD415 Biochemistry |
| Faculties/Schools: |
UK Campuses > Faculty of Science > School of Biosciences |
| Related URLs: |
|
| Item ID: |
64292 |
| Depositing User: |
Wakefield, Jennifer
|
| Date Deposited: |
31 Dec 2021 04:40 |
| Last Modified: |
15 Nov 2023 15:24 |
| URI: |
https://eprints.nottingham.ac.uk/id/eprint/64292 |
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