Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings

Sadeghimeresht, Esmaeil, Reddy, Liam, Hussain, Tanvir, Huhtakangas, Matti, Markocsan, Nicolaie and Joshi, Shrikant (2018) Influence of KCl and HCl on high temperature corrosion of HVAF-sprayed NiCrAlY and NiCrMo coatings. Materials & Design, 148 . pp. 17-29. ISSN 0264-1275

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Abstract

The oxidation performance of NiCrAlY and NiCrMo coatings thermally sprayed by high velocity air-fuel (HVAF) technique has been investigated in a chloridizing-oxidizing environment, with and without a KCl deposit, at 600 °C for up to 168 h. Both coatings protected the substrate in the absence of KCl due to formation of a dense Cr-rich oxide scale. In the presence of KCl, Cl−/Cl2 diffused through a non-protective and porous NiCr2O4 scale formed on NiCrAlY, leading to formation of volatile CrCl3. On the other hand, Mo in NiCrMo stimulated the formation of a more protective Cr-rich oxide scale which increased the corrosion resistance by reducing Cl−/Cl2 diffusion.

Item Type: Article
RIS ID: https://nottingham-repository.worktribe.com/output/938748
Keywords: Thermal spray coating; NiCrAlYNiCrMo; High-velocity air fuel (HVAF); Biomass-/waste-fired boiler; Fireside corrosion
Schools/Departments: University of Nottingham, UK > Faculty of Engineering > Department of Mechanical, Materials and Manufacturing Engineering
Identification Number: https://doi.org/10.1016/j.matdes.2018.03.048
Depositing User: Eprints, Support
Date Deposited: 09 Apr 2018 12:47
Last Modified: 04 May 2020 19:40
URI: https://eprints.nottingham.ac.uk/id/eprint/51038

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