Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration

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Callingham, Michael, Partridge, Benjamin M., Lewis, William and Lam, Hon Wai (2017) Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration. Angewandte Chemie International Edition, 56 (51). pp. 16352-16356. ISSN 1521-3773

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.201709334/abstract

Abstract

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.

Item Type:	Article
RIS ID:	https://nottingham-repository.worktribe.com/output/900327
Keywords:	arylboronic acid; 1,4-migration; imine
Schools/Departments:	University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number:	10.1002/anie.201709334
Depositing User:	Eprints, Support
Date Deposited:	16 Oct 2017 12:13
Last Modified:	04 May 2020 19:22
URI:	https://eprints.nottingham.ac.uk/id/eprint/47300

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