Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration

Tools

Korkis, Stamatis E., Burns, David J. and Lam, Hon Wai (2016) Rhodium-catalyzed oxidative C–H allylation of benzamides with 1,3-dienes by allyl-to-allyl 1,4-Rh(III) migration. Journal of the American Chemical Society . ISSN 1520-5126

Full text not available from this repository.

Abstract

The Rh(III)-catalyzed oxidative C–H allylation of N-acetylbenzamides with 1,3-dienes is described. The presence of allylic hydrogens cis- to the less substituted alkene of the 1,3-diene is important for the success of these reactions. With the assistance of reactions using deuterated 1,3-dienes, a proposed mechanism is provided. The key step is postulated to be the first reported examples of allyl-to-allyl 1,4-Rh(III) migration.

Item Type: Article
RIS ID: https://nottingham-repository.worktribe.com/output/804872
Additional Information: This document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see http://pubs.acs.org/page/policy/articlesonrequest/index.html
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: 10.1021/jacs.6b06884
Depositing User: Bramwell, Roseanna
Date Deposited: 05 Sep 2016 14:05
Last Modified: 04 May 2020 18:06
URI: https://eprints.nottingham.ac.uk/id/eprint/36246

Actions (Archive Staff Only)

Edit View Edit View