A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

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Perotto, Carlo U., Marshall, George, Jones, Graham J., Lewis, William, McMaster, Jonathan and Schröder, Martin (2015) A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51 . pp. 16988-16991. ISSN 1364-548X

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Abstract

Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.

Item Type: Article
RIS ID: https://nottingham-repository.worktribe.com/output/760231
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: 10.1039/c5cc05881c
Depositing User: Bramwell, Roseanna
Date Deposited: 30 Nov 2015 08:29
Last Modified: 04 May 2020 17:16
URI: https://eprints.nottingham.ac.uk/id/eprint/30939

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