Chain walking of allylrhodium species towards esters during rhodium-catalyzed nucleophilic allylations of imines

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Martínez, Jose I., Smith, Joshua S., Hepburn, Hamish B. and Lam, Hon Wai (2015) Chain walking of allylrhodium species towards esters during rhodium-catalyzed nucleophilic allylations of imines. Angewandte Chemie International Edition . ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.201508964/full

Abstract

Allylrhodium species derived from δ-trifluoroboryl β,γ-unsaturated esters undergo chain walking towards the ester moiety.The resulting allylrhodium species react with imines to give products containing two new stereocenters and a Z-alkene. By using a chiral diene ligand, products can be obtained with high enantioselectivities, where a pronounced matched/mismatched effect with the chirality of the allyltrifluoroborate is evident.

Item Type:	Article
RIS ID:	https://nottingham-repository.worktribe.com/output/770310
Schools/Departments:	University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number:	10.1002/anie.201508964
Depositing User:	Bramwell, Roseanna
Date Deposited:	09 Nov 2015 09:31
Last Modified:	04 May 2020 17:28
URI:	https://eprints.nottingham.ac.uk/id/eprint/30669

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