A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides

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Carbone, Giorgio, Burnley, James and Moses, John E. (2013) A catalytic and tert-butoxide ion-mediated amidation of aldehydes with para-nitro azides. Chemical Communications, 49 (27). pp. 2759-2761. ISSN 1364-548X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2013/CC/c3cc40452h

Abstract

We report here a new catalytic reaction in which, p-nitro azides are acylated by aldehydes to produce amides and molecular nitrogen in a single step. The transformation is believed to proceed via an electron transfer process mediated by the tert-butoxide ion, and catalysed by a thiazolium salt derived species.

Item Type:	Article
RIS ID:	https://nottingham-repository.worktribe.com/output/713402
Schools/Departments:	University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number:	10.1039/c3cc40452h
Depositing User:	Moses, Dr John
Date Deposited:	15 Jul 2013 08:17
Last Modified:	04 May 2020 16:35
URI:	https://eprints.nottingham.ac.uk/id/eprint/2050

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