Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration

Callingham, Michael and Partridge, Benjamin M. and Lewis, William and Lam, Hon Wai (2017) Enantioselective rhodium-catalyzed coupling of arylboronic acids, 1,3-enynes, and Imines by alkenyl-to-allyl 1,4-rhodium(I) migration. Angewandte Chemie International Edition, 56 (51). pp. 16352-16356. ISSN 1521-3773

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Abstract

A chiral rhodium complex catalyzes the highly enantioselective coupling of arylboronic acids, 1,3-enynes, and imines to give homoallylic sulfamates. The key step is the generation of allylrhodium(I) species by alkenyl-to-allyl 1,4-rhodium(I) migration.

Item Type: Article
Keywords: arylboronic acid; 1,4-migration; imine
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: https://doi.org/10.1002/anie.201709334
Depositing User: Eprints, Support
Date Deposited: 16 Oct 2017 12:13
Last Modified: 02 Jul 2018 09:16
URI: http://eprints.nottingham.ac.uk/id/eprint/47300

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