A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases

Perotto, Carlo U. and Marshall, George and Jones, Graham J. and Lewis, William and McMaster, Jonathan and Schröder, Martin (2015) A Ni(I)Fe(II) analogue of the Ni-L state of the active site of the [NiFe] hydrogenases. Chemical Communications, 51 . pp. 16988-16991. ISSN 1364-548X

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Abstract

Ni(L1)Fe(tBuNC)4](PF6)2 is a robust NiIIFeII complex that undergoes a reversible one-electron reduction. Spectroscopic and theoretical studies show that [Ni(L1)Fe(tBuNC)4]+ is an unprecedented NiIFeII species that reproduces the electronic configuration of the Ni-L state of the [NiFe] hydrogenases.

Item Type: Article
Schools/Departments: University of Nottingham UK Campus > Faculty of Science > School of Chemistry
Identification Number: https://doi.org/10.1039/c5cc05881c
Depositing User: Bramwell, Roseanna
Date Deposited: 30 Nov 2015 08:29
Last Modified: 25 Oct 2016 12:18
URI: http://eprints.nottingham.ac.uk/id/eprint/30939

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