N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis

Nolla Saltiel, Roberto (2019) N/P-based Sterically Demanding Ligands: Synthesis, Reactivity and Catalysis. PhD thesis, University of Nottingham.

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Abstract

This thesis details aims at forming low-coordinate metal complexes, stabilised by N-based ligands, with significant focus on carbazole based systems. The sysnthesis of ligands containing these moieties is first targeted, giving a detailed explanation of how differing synthetic pathways that allow modifications to the central carbazole core, in turn allow the formation of stable low-coordinate metal centres. Stabilised metal centres derived from these studies, have been found useful in the dehydrogenation of dimethylamine-borane adducts. While also suitable in the selective anti-Markovnikov hydrophosphination of activated alkenes.

Item Type: Thesis (University of Nottingham only) (PhD)
Supervisors: Kays, Deborah L.
Mcmaster, J
Keywords: ligands, carbazoles, alkali metal complexes
Subjects: Q Science > QD Chemistry > QD146 Inorganic chemistry
Faculties/Schools: UK Campuses > Faculty of Science > School of Chemistry
Item ID: 56541
Depositing User: Nolla Saltiel, Roberto
Date Deposited: 26 Apr 2022 09:08
Last Modified: 26 Apr 2022 09:10
URI: http://eprints.nottingham.ac.uk/id/eprint/56541

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