Post-functionalization of a photoactive hybrid polyoxotungstate

Cameron, Jamie M. and Fujimoto, Satomi and Wei, Rong-Jia and Newton, Graham N. and Oshio, Hiroki (2018) Post-functionalization of a photoactive hybrid polyoxotungstate. Dalton Transactions . ISSN 1477-9234

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Abstract

A new post-functionalization strategy for hybrid polyoxometalate (POM) clusters is presented, whereby the electronic properties and visible-light driven oxidative reactivity of the POM core can be altered by controlled addition of transition metal ions. The structure of three new metal-functionalised derivatives of a phosphonate hybrid-POM are discussed, alongside a comparison of their electrochemical, photo-chemical and photo-oxidative properties.

Item Type: Article
RIS ID: https://nottingham-repository.worktribe.com/output/932685
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: https://doi.org/10.1039/C8DT01253A
Depositing User: Smith, Ruth
Date Deposited: 08 Jun 2018 10:56
Last Modified: 04 May 2020 19:36
URI: http://eprints.nottingham.ac.uk/id/eprint/52302

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