Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration

Luo, Yunfei and Wales, Steven M. and Korkis, Stamatis E. and Roy, Iain D. and Lewis, William and Lam, Hon Wai (2018) Switchable synthesis of Z-homoallylic boronates and E-allylic boronates by enantioselective copper-catalyzed 1,6-boration. Chemistry - a European Journal, 24 (33). pp. 8315-8319. ISSN 1521-3765

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Abstract

The enantioselective Cu-catalyzed 1,6-boration of (E,E) α,β,γ,δ-unsaturated ketones is described, which gives homoallylic boronates with high enantiomeric purity and unexpectedly high Zselectivity. By changing the solvent, the outcome can be altered to give E-allylic boronates.

Item Type: Article
RIS ID: https://nottingham-repository.worktribe.com/output/938091
Keywords: 1,6-addition; asymmetric catalysis; boron; copper; enantioselectivity
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: https://doi.org/10.1002/chem.201801804
Depositing User: Smith, Ruth
Date Deposited: 20 Apr 2018 12:33
Last Modified: 04 May 2020 19:40
URI: http://eprints.nottingham.ac.uk/id/eprint/51268

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