Morphological characterisation of diesel soot in oil and the associated extraction dependence

Key, Sarah and La Rocca, Antonino and Fay, Mike and Rance, Graham and Growney, David (2018) Morphological characterisation of diesel soot in oil and the associated extraction dependence. In: WCX18: SAE World Congress Experience, 10-12 April 2018, Detroit, Michigan, USA.

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Abstract

The size and morphology of soot particles and agglomerates extracted from lubricating oil drawn from the sump of a diesel engine have been investigated and compared using Transmission Electron Microscopy (TEM) and Nanoparticle Tracking Analysis (NTA). Samples were prepared for electron microscopy imaging by both centrifugation and solvent extraction to investigate the impact of these procedures on the morphological characteristics, such as skeleton length and width and circularity, of the obtained soot. It was shown that centrifugation increases the extent of agglomeration within the sample, with 15% of the agglomerates above 200 nm compared to only 11% in the solvent extracted soot. It was also observed that the width of centrifugation extracted soot was typically 10 nm to 20 nm larger than that of solvent extracted soot, suggesting that centrifugation forces the individual agglomerate chains together. Moreover, centrifugation fails to extract a large percentage of particles below 50 nm, with only 4% of the agglomerates smaller than 50 nm in the centrifugation extracted soot, whereas agglomerates in this size range accounted for 19 % using solvent extraction. As TEM represents a comparatively time and cost expensive characterisation tool, unsuitable for high throughput testing required by industry, NTA was explored as a low cost, rapid alternative method for measuring particle size. It was found that results generated by NTA, within the limits of detection, correlated well with those obtained using TEM. This correlative electron microscopy and light scattering approach was further used to appraise the morphological characteristics of two commercial sources of carbon black (CB), enabling the selection of the most suitable soot surrogate, essential for the further development of oils with optimised functional properties.

Item Type: Conference or Workshop Item (Paper)
Additional Information: Key, S., La Rocca, A., Fay, M., Rance, G. et al., "Morphological Characterisation of Diesel Soot in Oil and the Associated Extraction Dependence," SAE Technical Paper 2018-01-0935, 2018, https://doi.org/10.4271/2018-01-0935.
Schools/Departments: University of Nottingham, UK > Faculty of Engineering
Identification Number: https://doi.org/10.4271/2018-01-0935
Related URLs:
URLURL Type
http://saeevents.org/events/wcx18-sae-world-congress-experienceUNSPECIFIED
https://www.sae.org/publications/technical-papers/content/2018-01-0935UNSPECIFIED
Depositing User: Eprints, Support
Date Deposited: 16 Apr 2018 13:26
Last Modified: 16 Apr 2018 13:30
URI: http://eprints.nottingham.ac.uk/id/eprint/51166

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