The singularity index for soil geochemical variables, and a mixture model for its interpretation

Lark, R.M. and Patton, M. and Ander, E.L. and Reay, D.M. (2018) The singularity index for soil geochemical variables, and a mixture model for its interpretation. Geoderma, 323 . pp. 83-106. ISSN 0016-7061

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Abstract

A geochemical anomaly is a concentration of an element or other constituent in a medium (soil, sediment or surface water) which is unusual in its local setting. Geochemical anomalies may be interesting as indicators of processes such as point contamination or mineralizations. They may therefore be practically useful, indicating sources of pollution or mineral deposits which may be of economic value. As defined, a geochemical anomaly is not merely a large (or small) concentration of a constituent as compared to the marginal distribution. To detect anomalies we must therefore do more than simply map the spatial distribution of the constituent. One proposed approach makes use of a singularity index based on fractal representation of spatial variation. The singularity index can be computed from local concentration measures in nested windows. In this paper we propose an approach to compute threshold values for the index to identify enrichment and depletion anomalies, separate from background information. The approach is based on a mixture model for the singularity index, and it can be supported by computing a distribution for background values of the index by parametric bootstrapping from a robustly-estimated variogram model for the target constituent. This approach is illustrated here using data on elements in the soil in four settings in Great Britain and Ireland.

Item Type: Article
Keywords: Geochemistry; Anomalies; Singularity; Fractal; Mixture model
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Biosciences
Identification Number: https://doi.org/10.1016/j.geoderma.2018.02.032
Depositing User: Eprints, Support
Date Deposited: 12 Apr 2018 09:44
Last Modified: 13 Apr 2018 18:11
URI: http://eprints.nottingham.ac.uk/id/eprint/51106

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