Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes

Nolla-Saltiel, Roberto and Geer, Ana M and Lewis, William and Blake, Alexander J. and Kays, Deborah L. (2018) Dehydrogenation of dimethylamine-borane mediated by Group 1 pincer complexes. Chemical Communications, 54 (15). pp. 1825-1828. ISSN 1364-548X

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Abstract

Group 1 salts containing carbazolido NNN pincer ligands are precatalysts for the dehydrogenation of Me2NH·BH3. NMR monitoring and DOSY studies show a heavy dependence on the metal and solvent, allowing in some cases selective formation of dehydrogenation products consistent with hydrogen liberation.

Item Type: Article
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: https://doi.org/10.1039/c7cc08385h
Depositing User: Smith, Ruth
Date Deposited: 16 Feb 2018 16:14
Last Modified: 16 Feb 2018 16:17
URI: http://eprints.nottingham.ac.uk/id/eprint/49825

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