Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines

Souto, José A. and Lewis, William and Stockman, Robert A. (2014) Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines. Chemical Communications, 50 (84). pp. 12630-12632. ISSN 1364-548X

[img]
Preview
PDF - Requires a PDF viewer such as GSview, Xpdf or Adobe Acrobat Reader
Download (748kB) | Preview

Abstract

The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate.

Item Type: Article
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: 10.1039/c4cc05751a
Depositing User: Lewis, William
Date Deposited: 25 Sep 2017 10:59
Last Modified: 14 Oct 2017 08:23
URI: http://eprints.nottingham.ac.uk/id/eprint/46644

Actions (Archive Staff Only)

Edit View Edit View