Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines

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Souto, José A., Lewis, William and Stockman, Robert A. (2014) Isolation of stable non cyclic 1,2-disulfoxides: revisiting the thermolysis of S-aryl sulfinimines. Chemical Communications, 50 (84). pp. 12630-12632. ISSN 1364-548X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2014/CC/C4CC05751A#!divAbstract

Abstract

The thermolysis of S-aryl sulfinimines is shown to generate 1,2-disulfoxides and disulfides via initial Cope elimination, dimerisation of the produced sulfenic acid to a thiosulfinate, and subsequent disproportionation of the thiosulfinate.

Item Type:	Article
RIS ID:	https://nottingham-repository.worktribe.com/output/733415
Schools/Departments:	University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number:	10.1039/c4cc05751a
Depositing User:	Lewis, William
Date Deposited:	25 Sep 2017 10:59
Last Modified:	04 May 2020 16:51
URI:	https://eprints.nottingham.ac.uk/id/eprint/46644

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