Triamidoamine-uranium(IV)-stabilized terminal parent phosphide and phosphinidene complexes

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Gardner, Benedict M., Balázs, Gábor, Scheer, Manfred, Tuna, Floriana, McInnes, Eric J.L., McMaster, Jonathan, Lewis, William, Blake, Alexander J. and Liddle, Stephen T. (2014) Triamidoamine-uranium(IV)-stabilized terminal parent phosphide and phosphinidene complexes. Angewandte Chemie International Edition, 53 (17). pp. 4484-4488. ISSN 1521-3773

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.201400798/abstract

Abstract

Reaction of [U(TrenTIPS)(THF)][BPh4] (1; TrenTIPS=N{CH2CH2NSi(iPr)3}3) with NaPH2 afforded the novel f-block terminal parent phosphide complex [U(TrenTIPS)(PH2)] (2; U–P=2.883(2) Å). Treatment of 2 with one equivalent of KCH2C6H5 and two equivalents of benzo-15-crown-5 ether (B15C5) afforded the unprecedented metal-stabilized terminal parent phosphinidene complex [U(TrenTIPS)(PH)][K(B15C5)2] (4; U[DOUBLE BOND]P=2.613(2) Å). DFT calculations reveal a polarized-covalent U[DOUBLE BOND]P bond with a Mayer bond order of 1.92.

Item Type:	Article
RIS ID:	https://nottingham-repository.worktribe.com/output/726691
Keywords:	density functional calculations; multiple bonds; phosphides; phosphinidene; uranium
Schools/Departments:	University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number:	10.1002/anie.201400798
Depositing User:	Lewis, William
Date Deposited:	28 Sep 2017 11:01
Last Modified:	04 May 2020 16:46
URI:	https://eprints.nottingham.ac.uk/id/eprint/46636

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