Enantioselective copper-catalyzed reductive coupling of vinylazaarenes with N-Boc aldimines

Choi, Bonnie and Saxena, Aakarsh and Smith, Joshua J. and Churchill, Gwydion H. and Lam, Hon Wai (2015) Enantioselective copper-catalyzed reductive coupling of vinylazaarenes with N-Boc aldimines. Synlett, 26 (3). pp. 350-351. ISSN 1437-2096

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Abstract

The diastereo- and enantioselective reductive coupling of vinylazaarenes with N-Boc aldimines is described. The reactions proceed using chiral copper–bisphosphine complexes in the presence of TMDS as a hydride source to give reductive coupling products in moderate to high enantioselectivities.

Item Type: Article
Additional Information: © 2015 Georg Thieme Verlag KG
Keywords: Asymmetric catalysis, Copper, Enantioselectivity, Imines, Vinylazaarenes
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: 10.1055/s-0034-1379548
Depositing User: Smith, Ruth
Date Deposited: 08 Jun 2017 14:55
Last Modified: 13 Oct 2017 00:10
URI: http://eprints.nottingham.ac.uk/id/eprint/43480

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