The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

Martin, Adam D. and Easun, Timothy L. and Argent, Stephen P. and Lewis, William and Blake, Alexander J. and Schröder, Martin (2016) The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene. CrystEngComm, 19 . pp. 603-607. ISSN 1466-8033

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Abstract

Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

Item Type: Article
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: 10.1039/C6CE01965J
Depositing User: Bramwell, Roseanna
Date Deposited: 25 Nov 2016 11:21
Last Modified: 06 May 2017 16:49
URI: http://eprints.nottingham.ac.uk/id/eprint/38947

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