The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene

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Martin, Adam D., Easun, Timothy L., Argent, Stephen P., Lewis, William, Blake, Alexander J. and Schröder, Martin (2016) The effect of carboxylate position on the structure of a metal organic framework derived from cyclotriveratrylene. CrystEngComm, 19 . pp. 603-607. ISSN 1466-8033

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2017/CE/C6CE01965J#!divAbstract

Abstract

Two cyclotriveratrylene-based ligands H3L1 and H3L2 have been synthesised using microwave heating and used in the formation of 1 [Zn2(L1)(DMA)2(CH3COO)] and 2 [Zn6(L2)4(DMA)6(H2O)5] (DMA = N,N-dimethylacetamide). 1 displays an unusual trigonal paddlewheel node geometry, while Zn(II) paddlewheels are observed in 2. However the stacking of CTV molecules in 1 is replaced by an uncommon molecular capsule structure in 2.

Item Type:	Article
RIS ID:	https://nottingham-repository.worktribe.com/output/828280
Schools/Departments:	University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number:	https://doi.org/10.1039/C6CE01965J
Depositing User:	Bramwell, Roseanna
Date Deposited:	25 Nov 2016 11:21
Last Modified:	04 May 2020 18:20
URI:	https://eprints.nottingham.ac.uk/id/eprint/38947

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