Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study

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O'Connor, Alice E., Mirzadeh, Nedaossadat, Bhargava, Suresh, Easun, Timothy L., Schröder, Martin and Blake, Alexander J. (2016) Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. Chemical Communications, 52 . pp. 6769-6772. ISSN 1364-548X

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Abstract

High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

Item Type: Article
RIS ID: https://nottingham-repository.worktribe.com/output/780678
Keywords: High pressure, gold complexes, structure determination, spectroscopy, intermolecular interactions
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: https://doi.org/10.1039/C6CC00923A
Depositing User: Bramwell, Roseanna
Date Deposited: 29 Jul 2016 11:13
Last Modified: 04 May 2020 17:42
URI: https://eprints.nottingham.ac.uk/id/eprint/35540

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