Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study

O'Connor, Alice E. and Mirzadeh, Nedaossadat and Bhargava, Suresh and Easun, Timothy L. and Schröder, Martin and Blake, Alexander J. (2016) Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. Chemical Communications, 52 . pp. 6769-6772. ISSN 1364-548X

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Abstract

High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

Item Type: Article
Keywords: High Pressure, Gold Complexes, Structure Determination, Spectroscopy, Intermolecular Interactions
Schools/Departments: University of Nottingham UK Campus > Faculty of Science > School of Chemistry
Identification Number: https://doi.org/10.1039/C6CC00923A
Depositing User: Bramwell, Roseanna
Date Deposited: 21 Mar 2016 13:38
Last Modified: 15 Sep 2016 18:49
URI: http://eprints.nottingham.ac.uk/id/eprint/32411

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