Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study

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O'Connor, Alice E., Mirzadeh, Nedaossadat, Bhargava, Suresh, Easun, Timothy L., Schröder, Martin and Blake, Alexander J. (2016) Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. Chemical Communications, 52 . pp. 6769-6772. ISSN 1364-548X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2016/CC/C6CC00923A#!divAbstract11

Abstract

High pressure crystallographic studies on [1,4 C6H4{PPh2(AuCl)}2] (1) reveal the largest pressure-induced contraction of an aurophilic interaction observed for any Au(I) complex; Hirshfeld surface analysis and Raman spectroscopy reveal the presence of several types of intermolecular interaction, which play an important role in the behaviour of 1 as a function of pressure.

Item Type:	Article
Keywords:	High Pressure, Gold Complexes, Structure Determination, Spectroscopy, Intermolecular Interactions
Schools/Departments:	University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number:	10.1039/C6CC00923A
Depositing User:	Bramwell, Roseanna
Date Deposited:	21 Mar 2016 13:38
Last Modified:	14 Oct 2017 07:54
URI:	https://eprints.nottingham.ac.uk/id/eprint/32411

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Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. (deposited 21 Mar 2016 13:38) [Currently Displayed]
- Aurophilicity under pressure: a combined crystallographic and in-situ spectroscopic study. (deposited 29 Jul 2016 11:13)

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