Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer

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Carbone, Giorgio, Burnley, James and Moses, John E. (2013) Catalytic reduction of ortho- and para-azidonitrobenzenes via tert-butoxide ion mediated electron transfer. SYNLETT, 24 (5). pp. 652-656. ISSN 0936-5214

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Abstract

The reduction of a range of substituted azidonitrobenzene derivatives to the corresponding aniline is described. The chemoselective reaction proceeds cleanly and in good yield, generating minimal waste products. The process involves a thiazolium salt derived species which is proposed as a radical anion relay, with tert-butoxide as the stoichiometric reductant.

Item Type: Article
RIS ID: https://nottingham-repository.worktribe.com/output/1003523
Schools/Departments: University of Nottingham, UK > Faculty of Science > School of Chemistry
Identification Number: https://doi.org/10.1055/s-0032-1318216
Depositing User: Moses, Dr John
Date Deposited: 15 Jul 2013 10:03
Last Modified: 04 May 2020 20:19
URI: https://eprints.nottingham.ac.uk/id/eprint/2051

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