New developments in the 1-aza-Diels-Alder reaction : versatile routes to pyridines
Hurst, Timothy E. (2008) New developments in the 1-aza-Diels-Alder reaction : versatile routes to pyridines. PhD thesis, University of Nottingham.
In Chapter one a review of the l-aza-Diels-Alder reaction is presented. The hetero Diels-Alder reaction of l-aza-l,3-butadienes with both alkene and alkyne dienophiles has been shown to be an efficient and versatile method for the preparation of a large range of nitrogen-containing six-membered heterocycles. The use of electron-rich 1- azadienes in the normal electron-demand Diels-Alder reaction is primarily examined, followed by a brief look at the synthetic applications of the inverse electron-demand process.
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