Laser photofragment spectroscopy of diatomic molecular ions
Gibbon, Timothy (1998) Laser photofragment spectroscopy of diatomic molecular ions. PhD thesis, University of Nottingham.
High resolution (< 0.005 cm−1) electronic spectra of the diatomic molecular ions 70GeH+ and 74GeH+ have been recorded using a fast ion beam irradiated by a cw tunable dye laser. Over 150 transitions between the ground X1∑ + state and near-threshold levels of electronic states correlating to the lowest dissociation asymptotes Ge+(2P3/2) + H(2S) and Ge+(2P1/2) + H(2S) were observed in the range 16500 cm−1 to 18500 cm−1.
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