The Enantioselective Generation of Bridgehead Enolates
Kirk, Douglas Thomas (2003) The Enantioselective Generation of Bridgehead Enolates. PhD thesis, University of Nottingham.
Chapter One gives an introduction to the key concepts of bridgehead alkene formation and its relevance to the formation of bridgehead enolates of ketones including a review of bridgehead enolates in synthesis. The review is limited to the generation of bridgehead carbanions alpha to a carbonyl group and does not cover bridgehead cations, radicals or any anions except those already mentioned. In addition, a brief introduction to chiral base methodology and a review of the latest developments is included.
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